Lake Chapala is in the Citala Rift of western Mexico, which in association with the Tepic-Zacoalco and Colima Rifts, form the well-known neotectonic Jalisco continental triple junction. The rifts are characterized by evidence for both paleo- and active hydrothermal activity. At the south shore of the lake, near the Los Gorgos sublacustrine hydrothermal field, there are two tar emanations that appear as small islands composed of solid, viscous and black bitumen. Aliquots of tar were analyzed by GC-MS and the mixtures are comprised of geologically mature biomarkers and an UCM. PAH and n-alkanes are not detectable. The biomarkers consist mainly of hopanes, gammacerane, tricyclic terpanes, carotane and its cracking products, steranes, and drimanes. The biomarker composition and bulk C isotope composition (δ13C = −21.4%) indicate an organic matter source from bacteria and algae, typical of lacustrine ecosystems. The overall composition of these tars indicates that they are hydrothermal petroleum formed from lacustrine organic matter in the deeper sediments of Lake Chapala exceeding 40 ka (14C) in age and then forced to the lakebed by tectonic activity. The absence of alkanes and the presence of an UCM with mature biomarkers are consistent with rapid hydrothermal oil generation and expulsion at temperatures of 200–250 °C. The occurrence of hydrothermal petroleum in continental rift systems is now well known and should be considered in future energy resource exploration in such regions. 相似文献
Sand-rich submarine fans are radial or curved in plan view depending on the slope of the basin floor. They occur isolated or in coalescing systems. The fans' average lateral extent measures close to 25 km and their thickness usually less than 300 m. The thickness of outer fan sequences averages around 120 m and that of middle fan successions around 160 m. Rarely reported inner fan sequences have a maximum thickness of 80 m.
The formation of sand-rich fans is closely related to tectonic activity. Their sediment is coarse-grained and compositionally immature as indicated by significant feldspar content due to close provenance and rapid transport by short rivers with a steep gradient controlled by tectonism. Tectonic activity also provides for narrow shelves making the fans relatively insensitive to sealevel changes. Formation of sand-rich fans typically occurs in restricted continental basins. The tectonic settings are highly variable. Sand-rich fans typically receive their sediment through submarine canyons which intercept sand from longshore drift and/or are fed more or less directly by regional rivers.
The type of ancient fan system (radial, curved, isolated, coalescing) may be identified through paleocurrent map plots, facies map sketches, recognition of lateral thickness variations and sediment influx centers, as well as lateral bed correlations defining the minimum fan extent.
Important in distinguishing different environments of ancient fans are detailed measured sections, their comparison and correlation. Channelized inner fan and middle fan deposits may be distinguished from the unchannelized outer fan successions through bed correlation tests which reflect their different stratigraphic architectures and bedding patterns. Bedding in outer fan deposits (lobes) is relatively simple, parallel, and regular. The lateral bed continuity is relatively high. Channel fills, especially those of middle fan distributary channels, display a complicated bedding pattern with vertical and lateral random distribution of channel fills, axial erosion, and bed convergence towards the channel margins. Channel fills exhibit only linear bed continuity. Thus, the probability in carrying out local to regional scale lateral bed correlations is almost exclusively limited to outer fan deposits.
The measured sections will help further distinguish fan environments by revealing: (1) different facies associations in outer fan sequences (mainly B, C and D) and middle fan successions (mainly A, B, C, D, and channel margin facies); (2) greater average bed and layer thicknesses in middle fan as opposed to outer fan successions (“bed” and “layer” as used herein); (3) more frequent amalgamation surfaces in channel fills than in unchannelized outer fan deposits; (4) more frequent tabular amalgamation surfaces in outer fan sections; (5) more frequent nontabular amalgamation surfaces in channel fills; and (6) more frequent dish structures in middle fan than outer fan successions.
Rarely exposed fan valley fills may be identified by coarse conglomerates. Moreover, in proximity to fan valley fills, relatively mud-rich sediments may be observed that derive from the depositional system of the basin slope. 相似文献
A suite of (Mn1-xFex)Nb2O6 (x=0, 0.05, 0.25, 0.50, 0.75, 1) columbite samples has been prepared by solid-state reaction from oxides. X-ray diffraction
and spectroscopic investigations have been carried out in order to gain different perspectives on how the solid solution adapts
at different length scales to cation mixing. X-ray powder diffraction and powder absorption IR spectroscopy data are presented.
The powder diffraction data show that there is no significant excess volume of mixing on the Fe–Mn columbite join. All the
unit-cell parameters decrease linearly as a function of increasing Fe content. Substitution of Fe2+ for the larger Mn2+ cation causes a decrease in the volume of the A polyhedron, which also becomes more regular with respect to both bond-length
and edge-length distortion parameters. No significant variation of the B site has been observed. Wavenumber shifts of the
IR peaks nearly all vary linearly with composition, consistent with linear variations of the lattice parameters. Line broadening
has been quantified by autocorrelation analysis of the IR spectra. This is interpreted as suggesting that there is some element
of local strain or positional disorder at the length scale of second or third nearest neighbours around sites occupied by
Fe. 相似文献
The rift history of the Salta basin is related to the evolution of the Central Andes and to the activity of the Pacific margin, owing to its geographic location. Sedimentation occurred from the Neocomian to the Paleogene, with deposits reaching up to 5,000 m in thickness. Paleoenvironmental analysis reveals an evolutionary history controlled by tectonic and climatic changes. Isolated grabens characterized the early synrift stage; differential subsidence provoked distinct environments in the southern and northern subbasins. In the southern subbasins, alluvial-fan, fluvial-fan and lacustrine deposits prevail, whilst in the northern subbasins eolian and fluvial environments dominate. During the Maastrichtian, two major factors controlled the basin fill: the decrease in tectonic subsidence and a relative sea-level rise as recorded in South America. An extensive and shallow Atlantic marine ingression installed a carbonate system coincident with mainly humid conditions until the Danian. Until the Middle Eocene, the fluvial and lacustrine environmental evolution of the sag basin was controlled especially by the alternation of temperate with dry and humid periods. Paleontological records reflect these climatic changes and show their relationship to the sedimentation regime. 相似文献
A series of geotechnical centrifuge physical modeling tests were performed to assess the potential use of a new cost-effective mechanically stabilized earth system for retrofitting marginally stable cohesive slopes. The proposed system utilizes the dual functions of reinforcement and drainage by directly inserting high strength non-woven geotextile strips into slopes, with little or no excavation required behind the slope face. The system significantly increases the factor of safety of potentially unstable cohesive slopes, and can be constructed at less expense and more rapidly than conventional mechanically stabilized earth systems. 相似文献
Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms. 相似文献
Mercury emissions from US coal-fired power plants will be regulated by the US Environmental Protection Agency (USEPA) before the end of the decade. Because of this, the control of Hg in coal is important. Control is fundamentally based on the knowledge of the amounts of Hg in mined, beneficiated, and as-fired coal. Eastern Kentucky coals, on a reserve district level, have Hg contents similar to the USA average for coal at mines. Individual coals show greater variation at the bench scale, with Hg enrichment common in the top bench, often associated with enhanced levels of pyritic sulfur. Some of the variation between parts of eastern Kentucky is also based on the position relative to major faults. The Pine Mountain thrust fault appears to be responsible for elemental enrichment, including Hg, in coals on the footwall side of the thrust.Eastern Kentucky coals shipped to power plants in 1999, the year the USEPA requested coal quality information on coal deliveries, indicate that coals shipped from the region have 0.09 ppm Hg, compared to 0.10 ppm for all delivered coals in the USA. On an equal energy basis, and given equal concentrations of Hg, the high volatile bituminous coals from eastern Kentucky would emit less Hg than lower rank coals from other USA regions. 相似文献
The Shah-Kuh granitic pluton of eastern Central Iran was emplaced 165 Ma ago, in an active continental margin setting. It is made of two main units: a granodioritic unit (SiO2=63–71 wt%) to the north–west and a syenogranitic unit (SiO2=73–77 wt%) to the south–east. The former unit displays seriate medium-grained textures and contains locally abundant mafic enclaves. The latter unit is medium- to coarse-grained and porphyritic, with 0.5–3 cm long K-feldspar megacrysts. Fine-grained granitic bodies are present in both units. The rocks are metaluminous to slightly peraluminous (I-type) and peraluminous (S-type) and belong to the ilmenite-series granites. Fractional crystallization appears to have been a very effective differentiation process in both units, and the fractionated mineral assemblages are determined by mass balance calculations. Isotopic data (Sri=0.7065 and εNdt=−2.5) are consistent with a young upper crustal protolith. Tin mineralization in sheeted quartz-tourmaline (-cassiterite) veins is spatially associated with the granodioritic unit. The veins formed by hydraulic fracturing when the granodioritic to monzogranitic magma became water-saturated and exsolved a fluid phase during crystallization. The reduced nature of this magma is responsible for the incompatible behaviour of Sn, likely to favour Sn concentration in the residual melt and then in the exsolved fluid. Another fluid phase was exsolved by the syenogranitic magma and was responsible for local greisenized granites, characterized by high Y and HREE-contents and non-fractionated REE distribution patterns. Field and mineralogical data show that the (B, Sn) vein-forming fluid was different from the (F, Li) greisen-forming fluid. 相似文献
